{"created":"2023-06-19T08:46:15.189910+00:00","id":5028,"links":{},"metadata":{"_buckets":{"deposit":"32b457c7-cbab-4ae6-a089-8cd365ca93cb"},"_deposit":{"created_by":14,"id":"5028","owners":[14],"pid":{"revision_id":0,"type":"depid","value":"5028"},"status":"published"},"_oai":{"id":"oai:kpu.repo.nii.ac.jp:00005028","sets":["47:273:423"]},"author_link":["8049","7646"],"control_number":"5028","item_1696926521561":{"attribute_name":"その他（別言語等）","attribute_value_mlt":[{"subitem_alternative_title":"ヒメジオンのチオバルビツール酸反応物質(農芸化学部門)","subitem_alternative_title_language":"ja"}]},"item_3_biblio_info_12":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1979-12-20","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"152","bibliographicPageStart":"142","bibliographicVolumeNumber":"31","bibliographic_titles":[{"bibliographic_title":"京都府立大學學術報告. 農學","bibliographic_titleLang":"ja"},{"bibliographic_title":"The scientific reports of Kyoto Prefectural University. Agriculture","bibliographic_titleLang":"en"}]}]},"item_3_description_10":{"attribute_name":"抄録(日)","attribute_value_mlt":[{"subitem_description":"ヒメジオンの直接酸加水分解物を, イオン交換(アンバーライトIR-120とダウエックス1×2)クロマトグラフィーと, セファデックスG-15を用いるゲルロ過で分画した。得られたチオバルビツール酸反応陽性画分は, オボムチンのシアル酸と比較するため, 各種の分析に供された。その結果, ヒメジオンの酸加水分解物からは, シアル酸が検出されなかった。得られたチオバルビツール酸反応陽性物質の構造は, 分子量の測定, TBAテストによる発色団の同定, 赤外吸収, NMRスペクトル, 元素分析, 過ヨード酸酸化, 官能基の検索および各種の呈色反応などの結果から, HOCH_2 (CHOH)_5CH_2COCOOHと決定された。この化合物は, クロマトグラフ的にも呈色反応的にも, シアル酸に非常によく類似した性質を有していた。","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_3_description_11":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"Erigeron was hydrolyzed in acid directly, and the acid hydrolysate was fractionated by ion-exchange chromatography (Amberlite IR-120 and Dowex 1×2) and by gel filtration using Sephadex G-15. The gel filtrated TBA positive fraction was submitted to analysis for comparison with sialic acid from ovomucin. Sialic acid was not detected in Erigeron. The structure of TBA positive fraction can be formulated as HOCH_2 (CHOH)_5CH_2COCOOH according to molecular weight determination, identification of chromogen in TBA test, IR absorption, NMR spectra, elementary analysis, periodate oxidation, analysis of functional groups, some coler reaction and so on. This compound showed rather similar properties to sialic acid in chromatographic and colorimetric method of analysis.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_3_source_id_1":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00062275","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_20":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00757373","subitem_source_identifier_type":"PISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"金森, 正雄","creatorNameLang":"ja"},{"creatorName":"カナモリ, マサオ","creatorNameLang":"ja-Kana"},{"creatorName":"Kanamori, Masao","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"三好, 正満","creatorNameLang":"ja"},{"creatorName":"ミヨシ, マサミツ","creatorNameLang":"ja-Kana"},{"creatorName":"Miyoshi, Masamitsu","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-20"}],"displaytype":"detail","filename":"KJ00000079027.pdf","filesize":[{"value":"761.5 kB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"label":"KJ00000079027.pdf","url":"https://kpu.repo.nii.ac.jp/record/5028/files/KJ00000079027.pdf"},"version_id":"8f7f01dd-9144-4287-9d77-6937915099c6"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper"}]},"item_title":"Thiobarbituric acid reacting material in Erigeron annuus pers (Agricultural Chemistry)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Thiobarbituric acid reacting material in Erigeron annuus pers (Agricultural Chemistry)","subitem_title_language":"en"}]},"item_type_id":"3","owner":"14","path":["423"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-02-20"},"publish_date":"2017-02-20","publish_status":"0","recid":"5028","relation_version_is_last":true,"title":["Thiobarbituric acid reacting material in Erigeron annuus pers (Agricultural Chemistry)"],"weko_creator_id":"14","weko_shared_id":-1},"updated":"2024-04-24T06:16:33.364270+00:00"}