{"created":"2023-06-19T08:46:06.665518+00:00","id":4829,"links":{},"metadata":{"_buckets":{"deposit":"d0d0f3bc-909a-4b03-b89b-439d71719492"},"_deposit":{"created_by":4,"id":"4829","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"4829"},"status":"published"},"_oai":{"id":"oai:kpu.repo.nii.ac.jp:00004829","sets":["47:273:412"]},"author_link":["7847","7846"],"control_number":"4829","item_1696926521561":{"attribute_name":"その他（別言語等）","attribute_value_mlt":[{"subitem_alternative_title":"飽気木材中の溶質拡散 II : 電解質の拡散におよぼす温度の影響(林学部門)","subitem_alternative_title_language":"ja"}]},"item_3_biblio_info_12":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1968-10-15","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"67","bibliographicPageStart":"57","bibliographicVolumeNumber":"20","bibliographic_titles":[{"bibliographic_title":"京都府立大學學術報告. 農學","bibliographic_titleLang":"ja"},{"bibliographic_title":"The scientific reports of Kyoto Prefectural University. Agriculture","bibliographic_titleLang":"en"}]}]},"item_3_description_10":{"attribute_name":"抄録(日)","attribute_value_mlt":[{"subitem_description":"前報に続き, 飽水木材中の溶質拡散に及ぼす温度の影響を2種の電解質(Na-PCP, KCl)を用い, 25&acd;70℃の温度範囲にわたり, ヒノキおよびブナ材の3構造方向について検討した。測定装置は拡散セルや電気抵抗の測定回路における若干の改良を除いては前報のそれと全く同様であり, 測定には直径4cm, 厚さ1cm(拡散方向が繊維方向)および0.15cm(拡散方向が半径および切線方向)の円板形の試験片を供試した。得られた結果を要約すると次の通りである。(1)時間-透過量曲線をプロットした場合, 定常状態における測定値の変動は2.0%以下であった(Fig. 2)。(2) log D-1/T曲線をプロットした場合, ヒノキ材のR-方向におけるNa-PCPの拡散を除いては近似的に直線関係が得られた(Fig. 3,Fig. 4)。(3)ヒノキ材ではT-方向とR-方向の拡散係数に差異が認められなかったが, ブナ材の場合にはT-方向の拡散速度はR-方向のそれの約2倍であった。また, 両材のL-方向の拡散速度はT-およびR-方向のそれの5&acd;36倍であった(Table 3)。(4) KClの拡散係数はNa-PCPのそれよりもかなり大きく, とくにこの傾向はT-およびR-方向の拡散において顕著であった(Table 4)。(5)拡散の見かけの活性化エネルギーおよび平均の温度係数についてみると, 一般にNa-PCPはKClよりも, またT-およびR-方向のそれはL-方向よりも大きく, とくにこの傾向はヒノキ材において顕著であった(Table 5)。(6)木材中の溶質の拡散速度は拡散通路内に存在する有効毛管の毛管径とその数に支配される。また, 拡散の見かけの活性化エネルギーや平均の温度係数は個々の有効毛管, とくに分子やイオンの自由拡散経路の寸法, および単位拡散距離中に通過する自由拡散経路の直径以下の毛管数に関係することが推測された。","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_3_description_11":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"The effects of temperature on the diffusion of sodium pentachlorophenate (Na-PCP) and potassium chloride (KCl) through water-saturated wood have been measured in the three structural directions of Hinoki and Buna wood over a temperature range of 25-70℃. The apparatus used in these experiments was the same as that described in a previous report except for some modifications in the design of the diffusion cell and electric circuit. The test specimens were disks the size of 4cm in diameter, and 1cm (for longitudinal diffusion) or 0.15cm (for transverse diffusion) in thickness. The results obtained are as follows : (1) The deviations of measured values in the diffusion curves at each steady state, i.e. the coefficients of variation for regression coefficient in the amount of solute-transfer vs. time curves were less than 2 per cent (Fig. 2). (2) A plot of log D ((cm)^2/day×(10)^<-3>) against 1/T showed approximately linear relationship except for the diffusion of Na-PCP in R-direction of Hinoki (Fig. 3 and 4). (3) There was no difference in the diffusion coefficients between T- and R-directions of Hinoki, while the tangential diffusion coefficient of Buna was about twice as great as the radial value. The longitudinal diffusion coefficients of both the species were approximately 5-36 times as great as the transverse values (Table 3). (4) The diffusion rate of KCl was appreciably greater than that of Na-PCP in all cases. This tendency was especially more pronounced in the case of transverse diffusion (Table 4). (5) The apparent activation energy and the mean temperature coefficient in the diffusion process of Na-PCP were slightly greater than the corresponding values of KCl; further those of transverse diffusion were generally greater than values in longitudinal diffusion. In particular, these phenomena were remarkable in Hinoki (Table 5). (6) It was assumed that the apparent activation energy and the mean temperature coefficient in the diffusion process of electrolytes might be dependent upon the dimensions of the individual effective capillaries. Particularly they might be depend upon the mean free path of the solute traversed per unit distance in the diffusion direction, and also the number of capillaries whose radius was smaller than that of the mean free path.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_3_source_id_1":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00062275","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_20":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00757373","subitem_source_identifier_type":"PISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"福山, 萬治郎","creatorNameLang":"ja"},{"creatorName":"フクヤマ, マンジロウ","creatorNameLang":"ja-Kana"},{"creatorName":"Fukuyama, Manjiro","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"佐道, 健","creatorNameLang":"ja"},{"creatorName":"サドウ, タケシ","creatorNameLang":"ja-Kana"},{"creatorName":"Sadoh, Takesi","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-20"}],"displaytype":"detail","filename":"KJ00000078828.pdf","filesize":[{"value":"838.1 kB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"label":"KJ00000078828.pdf","url":"https://kpu.repo.nii.ac.jp/record/4829/files/KJ00000078828.pdf"},"version_id":"1c843cec-72f2-4c2d-bee4-79bc76c34d27"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper"}]},"item_title":"The diffusion of solute through wood saturated with water II : Effects of temperature on the diffusion of electrolytes (Forestry)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"The diffusion of solute through wood saturated with water II : Effects of temperature on the diffusion of electrolytes (Forestry)","subitem_title_language":"en"}]},"item_type_id":"3","owner":"4","path":["412"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-02-20"},"publish_date":"2017-02-20","publish_status":"0","recid":"4829","relation_version_is_last":true,"title":["The diffusion of solute through wood saturated with water II : Effects of temperature on the diffusion of electrolytes (Forestry)"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2024-05-15T06:38:11.857238+00:00"}